An enantioselective synthesis of 1′,1′a-methano carbocyclic thymidine, a rigid molecule that mimics thymidine's 2′-endo/3′-exo(South) conformation, is efficiently synthesized from chiral 2-benzyloxymethylcyciopent-3-enol.
A. Ezzitouni, J. J. Barchi and V. E. Marquez, J. Chem. Soc., Chem. Commun., 1995, 1345 DOI: 10.1039/C39950001345
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