Lactone 3, easily prepared from hydroxy-β-ionone, is transformed into the Ziegler intermediate in forskolin synthesis by a straightforward strategy involving two new rearrangements.
M. Leclaire, F. Pericaud and J. Y. Lallemand, J. Chem. Soc., Chem. Commun., 1995, 1333 DOI: 10.1039/C39950001333
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