[cis-Pt(C6F5)2(C
CPh)2]2– as a double alkynyl transfer reagent. Synthesis and characterization of the Ir(III)-Pt(II) Tweezer complex {[(η5-C5Me5)(PEt3)Ir(C
CPh)2]Pt(C6F5)2}
Abstract
[cis-Pt(C6F5)2(C
CPh)2]2– reacts with [Ir(C5Me5)(PEt3)(Me2CO)2](ClO4)2, via a double alkynylation process, yielding {[η5-C5Me5)(PEt3) Ir(C
CPh)2]Pt(C6F5)2} in which the alkynyl groups are σ bonded to the iridium centre and π bonded to the platinum one.
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CPh)2]2– as a double alkynyl transfer reagent. Synthesis and characterization of the Ir(III)-Pt(II) Tweezer complex {[(η5-C5Me5)(PEt3)Ir(C