SCHEDULED MAINTENANCE
Bis(2,4,6-triisopropylphenyl)stannylene, formed by thermolysis of the cyclotristannane 4, reacts with 4,5-dimethyl-1,3-diisopropylimidazol-2-ylidene to furnish the adduct 8; an X-ray structural analysis of this compound reveals the presence of a long tin–carbon ‘double bond’ with a length of 237. 9(5) pm and a distinctly pyramidal tin centre.
A. Schäfer, M. Weidenbruch, W. Saak and S. Pohl, J. Chem. Soc., Chem. Commun., 1995, 1157 DOI: 10.1039/C39950001157
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