Issue 10, 1995

Reaction of sodium alkoxides with [60]fullerene: formation of a 1,3-dioxolane derivative and involvement of O2 in a nucleophilic addition reaction of C60

Abstract

[60]Fullerene reacts with PhCH2ONa–PhCH2OH in the presence of air to afford a 1,3-dioxolane derivative of C60, which was characterized by FD-MS, FTIR, UV–VIS, 1H NMR, 13C MMR, HMQC and HMBC; a possible reaction mechanism is discussed.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1071-1072

Reaction of sodium alkoxides with [60]fullerene: formation of a 1,3-dioxolane derivative and involvement of O2 in a nucleophilic addition reaction of C60

G. Wang, L. Shu, S. Wu, H. Wu and X. Lao, J. Chem. Soc., Chem. Commun., 1995, 1071 DOI: 10.1039/C39950001071

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