Copper(I) oxide reacts with selenol 2,4,6-Pri3C6H2-SeH in ethanol to give the hexanuclear copper(I) selenolate {Cu[Se(2,4,6-Pri3C6H2)]}6 of 6, the solid state structure of which consists of a disordered Cu6 octahedron embedded in an antiprism formed by six selenium centres of the selenolate residues; this leads us to propose an exchange mechanism for the equilibration of all copper positions.
D. Ohlmann, H. Pritzkow, H. Grützmacher, M. Anthamatten and R. Glaser, J. Chem. Soc., Chem. Commun., 1995, 1011 DOI: 10.1039/C39950001011
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