Issue 9, 1995

Intramolecular cyclizations of α-stannyl radicals to acylsilanes: regiospecific syntheses of five-membered cyclic silyl enol ethers

Abstract

α-Stannyl radicals generated from acylsilanes 5, 13 and 14 cyclize to give good yields of cyclic silyl enol ethers after sequential cyclizations, radical Brook rearrangements and β-scissions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 981-982

Intramolecular cyclizations of α-stannyl radicals to acylsilanes: regiospecific syntheses of five-membered cyclic silyl enol ethers

Y. Tsai and S. Chang, J. Chem. Soc., Chem. Commun., 1995, 981 DOI: 10.1039/C39950000981

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