Issue 8, 1995

Efficient dimethyl malonate synthesis by methoxycarbonylation of dichloromethane catalysed by electrogenerated [Co(CO)3PBu3] species

Abstract

Electrochemistry is used for the synthesis of [Co(CO)3PBu3] complex in a methanol–methyl formate medium, which catalyses the alkoxycarbonylation of dichloromethane to dimethyl malonate in up to 75% yield.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 847-848

Efficient dimethyl malonate synthesis by methoxycarbonylation of dichloromethane catalysed by electrogenerated [Co(CO)3PBu3] species

P. Suisse, S. Pellegrini, Y. Castanet, A. Mortreux and S. Lecolier, J. Chem. Soc., Chem. Commun., 1995, 847 DOI: 10.1039/C39950000847

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