Issue 7, 1995

Synthetic studies related to the esperamicin/calicheamicin aglycone: efficient construction of a homochiral oxabicyclo [7 : 3 : 1] analogue from D-xylose

Abstract

The synthesis of a bicyclic model of the calicheamicin/esperamicin aglycone is described using a highly efficient and stereospecific Nozaki–Kishi reaction for the ring closure.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 799-800

Synthetic studies related to the esperamicin/calicheamicin aglycone: efficient construction of a homochiral oxabicyclo [7 : 3 : 1] analogue from D-xylose

I. Dancy, T. Skrydstrup, C. Crévisy and J. Beau, J. Chem. Soc., Chem. Commun., 1995, 799 DOI: 10.1039/C39950000799

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