Issue 6, 1995

Self-assembly of homochiral double helix and side-by-side helix conformers of a double-stranded disilver(I)–tetra(tertiary phosphine) complex

Abstract

Optically pure (S,S)-(+)-Ph2PCH2CH2P(Ph)CH2CH2P(Ph)CH2CH2PPh2, (S,S)-1, spontaneously self-assembles into left-handed double-stranded D2-double helix and C2-side-by-side helix conformers of the disilver(I) cation; the crystal and molecular structure of Λ-(–)-[Ag2{(R,R)-1}2][PF6]2 is reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 695-696

Self-assembly of homochiral double helix and side-by-side helix conformers of a double-stranded disilver(I)–tetra(tertiary phosphine) complex

A. L. Airey, G. F. Swiegers, A. C. Willis and S. B. Wild, J. Chem. Soc., Chem. Commun., 1995, 695 DOI: 10.1039/C39950000695

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