Issue 6, 1995

Stereoselective cyclopropanation of 1-azadienes with Fischer carbene complexes

Abstract

1-Aza-1,3-dienes, including a 1-aza-1,3,5-triene, are cyclopropanated by pentacarbonyl(methoxy)phenylchromium to give trans-cyclopropaneimines stereoselectively; their transformation into cyclopropane aldehydes and five-membered heterocycles is also described.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 665-666

Stereoselective cyclopropanation of 1-azadienes with Fischer carbene complexes

J. Barluenga, M. Tomás, J. A. López-Pelegrín and E. Rubio, J. Chem. Soc., Chem. Commun., 1995, 665 DOI: 10.1039/C39950000665

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