Issue 6, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

Utility of diene-tricarbonyliron complexes as mobile chiral auxiliaries: highly diastereoselective 1,5-nucleophilic substitution with 1,2-migration of the Fe(CO)3 moiety

Yoshiji Takemoto,   Naoki Yoshikawa  and  Chuzo Iwata  

Abstract

O-Acyl or O-phosphoryl cyanohydrin derivatives of the tricarbonyliron complex of hexa-2,4-dienal undergo regio- and stereo-selective 1,5-substitution reactions with several heteroatomic nucleophiles giving, with migration of the Fe(CO)3 group, predominantly either (E,E)- or (E,Z)- products by appropriate selection of solvent and acid catalyst.

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Article information

DOI
https://doi.org/10.1039/C39950000631
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 631-632

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Utility of diene-tricarbonyliron complexes as mobile chiral auxiliaries: highly diastereoselective 1,5-nucleophilic substitution with 1,2-migration of the Fe(CO)3 moiety

Y. Takemoto, N. Yoshikawa and C. Iwata, J. Chem. Soc., Chem. Commun., 1995, 631 DOI: 10.1039/C39950000631

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