The enantiopure iron complex 4 reacts under the influence of BF3·OEt2 with allylsilanes and enol acetates through a cationic intermediate in which the chirality of 4 is preserved, yielding enantiopure 5-substituted 3-pyrrolin-2-ones.
J. C. P. Hopman, H. Hiemstra and W. N. Speckamp, J. Chem. Soc., Chem. Commun., 1995, 617 DOI: 10.1039/C39950000617
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