Issue 5, 1995

Synthesis of γ-hydroperoxy-α,β-unsaturated carbonyl compounds from α,β,γ,δ-unsaturated carbonyl compounds by cobalt(II) porphyrin-catalysed hydroperoxygenation

Abstract

γ-Hydroperoxy-α,β-unsaturated carbonyl compounds are prepared in good yields by the regioselective hydroperoxygenation of α,β,γ,δ-unsaturated carbonyl compounds with molecular oxygen and triethylsilane in the presence of cobalt(II) porphyrin as a catalyst.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 567-568

Synthesis of γ-hydroperoxy-α,β-unsaturated carbonyl compounds from α,β,γ,δ-unsaturated carbonyl compounds by cobalt(II) porphyrin-catalysed hydroperoxygenation

Y. Matsushita, K. Sugamoto, T. Nakama and T. Matsui, J. Chem. Soc., Chem. Commun., 1995, 567 DOI: 10.1039/C39950000567

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