The aerobic oxidation of the manganese(III) dihydrosalen-thioether chelate rac-1 affords the novel manganese(III) sulfoxide complex rac-2; X-ray structural analysis of the latter reveals that only one of the two possible diastereomeric oxidation products is present in the crystal.
A. Berkessel, M. Bolte and T. Schwenkreis, J. Chem. Soc., Chem. Commun., 1995, 535 DOI: 10.1039/C39950000535
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