RuIII(NH3)6 in the cages of NaX zeolite is converted in the presence of CO + H2 into [Ru6(CO)18]2–, which is reversibly fragmented and reconstructed under oxidative and reductive conditions, respectively.
A.-M. Liu, T. Shido and M. Ichikawa, J. Chem. Soc., Chem. Commun., 1995, 507 DOI: 10.1039/C39950000507
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