A tetrathiol bowl-shaped cavitand and a derived carceplex
Abstract
The syntheses and characterization of tetrathiol bowl 4, its rearranged byproduct 6 and its derived carceplex 7⊙Me2NCOMe·4PhNO2 are reported, and the crystal structure of this carceplex is compared to that of its oxygen analogue, 8⊙Me2NCOMe·5CHCl3.