Isomeric cycloheptatrienols 1, 2 and 3 are found to undergo ketonizations as well as diazo-coupling reactions via three different pathways; experiments and ab initio calculations suggest that the 2-hydroxy group provides a small but effective stabilization effect on norcaradiene 11.
C. S. Q. Lew, T. Tang, I. G. Csizmadia and B. Capon, J. Chem. Soc., Chem. Commun., 1995, 175 DOI: 10.1039/C39950000175
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