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Even under normal pressures (1.5–3.0 atm), methanol is formed by the gas phase reaction of methane with oxygen in a flow quartz reactor at 425–490 °C with methanol selectivities exceeding 30% at a methane conversion of 5%.
L. Han, S. Tsubota, T. Kobayashi and M. Haruta, J. Chem. Soc., Chem. Commun., 1995, 93 DOI: 10.1039/C39950000093
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