Issue 1, 1995

Tris(2,6-diisopropylphenylimido) complexes of molybdenum: kinetic accessibility of the d0 Mo([double bond, length half m-dash]NR)3 functional group

Abstract

The unprecedented tris(imido) complex of molybdenum, [Li(THF)4][Mo(NAr)3Cl](Ar = C6H3Pri2-2,6), is the kinetic product of the reaction between [Mo(NAr)2Cl2(THF)2] and 2 equiv. of LiNHAr in THF; [Li(THF)4][Mo(NAr)3Cl] and byproduct H2NAr react further to form the thermodynamic product [Mo(NAr)2(NHAr)2].

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 79-80

Tris(2,6-diisopropylphenylimido) complexes of molybdenum: kinetic accessibility of the d0 Mo([double bond, length half m-dash]NR)3 functional group

D. L. Morrison and D. E. Wigley, J. Chem. Soc., Chem. Commun., 1995, 79 DOI: 10.1039/C39950000079

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