1,3-Dicarbonyls, such as 1,3-diketones and 1,3-ketoesters, react directly with elemental fluorine at room temperature to give the corresponding 2-fluoro- and, in some cases, 2,2-difluoro-compounds in high yield.
R. D. Chambers, M. P. Greenhall and J. Hutchinson, J. Chem. Soc., Chem. Commun., 1995, 21 DOI: 10.1039/C39950000021
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