Ketones 3a–c exhibit syn-face selectivity in borohydride reduction; MNDO and ab initio calculations on model and realistic transition states, respectively, reproduce the preference, but differ on the role of electrostatic and orbital effects.
G. Mehta, F. A. Khan, B. Ganguly and J. Chandrasekhar, J. Chem. Soc., Perkin Trans. 2, 1994, 2275 DOI: 10.1039/P29940002275
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