Jump to main content
Jump to site search

Issue 21, 1994
Previous Article Next Article

The phosphorylation of organic compounds by phosphoric anhydride. Part 3. Synthesis of monosubstituted ketenes in the reaction of esters with phosphoric anhydride and cyclotrimerization of these ketenes

Abstract

Monosubstituted ketenes 1 have been synthesized from substituted acetic esters 2 by elimination of alcohol under the action of phosphoric anhydride. The ketenes undergo cyclotrimerization to give substituted phloroglucinols (1,3,5-trihydroxybenzenes)3 and their phosphorylated derivatives.

Back to tab navigation

Article type: Paper
DOI: 10.1039/P19940003163
J. Chem. Soc., Perkin Trans. 1, 1994, 3163-3168

  •   Request permissions

    The phosphorylation of organic compounds by phosphoric anhydride. Part 3. Synthesis of monosubstituted ketenes in the reaction of esters with phosphoric anhydride and cyclotrimerization of these ketenes

    D. A. Efremov, P. M. Zavlin, N. S. Essentseva and J. C. Tebby, J. Chem. Soc., Perkin Trans. 1, 1994, 3163
    DOI: 10.1039/P19940003163

Search articles by author

Spotlight

Advertisements