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The labelling pattern arising from incorporation of [1,2-13C2]acetate into astellatol, a novel sesterterpenoid fungal metabolite, supports its biosynthesis via cyclisation and subsequent rearrangement of geranylfarnesyl pyrophosphate, and allows its relationship to a number of other fungal sesterterpenoids to be proposed.
T. J. Simpson, J. Chem. Soc., Perkin Trans. 1, 1994, 3055 DOI: 10.1039/P19940003055
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