Issue 13, 1994

A study of the intramolecular stille cross coupling reaction of vinylstannyl chloroformates: application to the synthesis of α-methylene lactones

Abstract

An intramolecular Stille cross coupling of vinylstannyl chloroformates catalysed by trans-benzylchlorobis(triphenylphosphine)palladium(II) has been investigated and shown to be useful for the preparation of α-methylene lactones. A novel method for the chloroformylation of alcohols in the presence of vinylstannanes is also described.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1994, 1697-1701

A study of the intramolecular stille cross coupling reaction of vinylstannyl chloroformates: application to the synthesis of α-methylene lactones

R. M. Adlington, J. E. Baldwin, A. Gansäuer, W. McCoull and A. T. Russell, J. Chem. Soc., Perkin Trans. 1, 1994, 1697 DOI: 10.1039/P19940001697

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