The high-pressure Diels–Alder reaction of fullerite with tropone and several of its derivatives under 300 MPa gave 1 : 1-[4 + 2] cycloadducts of C60 in good yields. Their 1H and 13C NMR spectra were consistent with the structures depicted. These compounds quantitatively regenerate starting materials upon thermolysis.
H. Takeshita, J. Liu, N. Kato, A. Mori and R. Isobe, J. Chem. Soc., Perkin Trans. 1, 1994, 1433 DOI: 10.1039/P19940001433
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