Cycloaddition of the nitrone, derived from tetradecanal, to 2-aminobut-3-en-1-ol provides a practical asymmetric synthesis of both (2R,4R,5S)-tetrahydropseudodistomin and all the stereoisomers of racemic tetrahydropseudodistomin.
T. Naito, M. Ikai, M. Shirakawa, K. Fujimoto, I. Ninomiya and T. Kiguchi, J. Chem. Soc., Perkin Trans. 1, 1994, 773 DOI: 10.1039/P19940000773
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