Highly functionalized optically pure bicyclo[3.1.0]hexan-2-ones 6a and 6b are easily obtained by the Intramolecular cyclopropanation of a D-ribose derivative using the iodonium ylide or diazo compound methods, which afford the final products with opposite diastereoselectivities.
J. K. Gallos, T. V. Koftis and A. E. Koumbis, J. Chem. Soc., Perkin Trans. 1, 1994, 611 DOI: 10.1039/P19940000611
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