Issue 3, 1994

Reaction of silyl enol ethers with arenediazonium salts. Part 2. α-Amination of esters

Abstract

Diazonium salts efficiently serve as electrophilic aminating reagents of esters. The reaction of arenediazonium tetrafluoroborates with ketene silyl ketals yielded α-azo or α-hydrazono esters in good to excellent yields under very mild conditions. Hydrogenation of those esters gave α-amino esters quantitatively.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1994, 289-293

Reaction of silyl enol ethers with arenediazonium salts. Part 2. α-Amination of esters

T. Sakakura, M. Hara and M. Tanaka, J. Chem. Soc., Perkin Trans. 1, 1994, 289 DOI: 10.1039/P19940000289

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