Issue 17, 1994
From the journal:

Journal of the Chemical Society, Faraday Transactions

Exchange of strong carbon dioxide O [double bond, length as m-dash] C bonds on an MgO surface

Yasunori Yanagisawa,   Katsutosi Takaoka  and  Shinichi Yamabe  

Abstract

Thermal desorption (TD) of 16O[double bond, length as m-dash]C[double bond, length as m-dash]18O and 16O[double bond, length as m-dash]C[double bond, length as m-dash]16O gases after 18O[double bond, length as m-dash]C[double bond, length as m-dash]18O adsorption on MgO powders has been observed in the temperature range 350–1000 K. [graphic omitted]. These two exchange reactions were investigated by ab initio calculations with various cluster models including a coordinatively unsaturated oxygen site. The single exchange is found to take place via a bidentate CO3 intermediate, and the double one proceeds with CO3 migration on the surface.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/FT9949002561
Article type
Paper

J. Chem. Soc., Faraday Trans., 1994,90, 2561-2566

Permissions

Request permissions

Exchange of strong carbon dioxide O [double bond, length as m-dash] C bonds on an MgO surface

Y. Yanagisawa, K. Takaoka and S. Yamabe, J. Chem. Soc., Faraday Trans., 1994, 90, 2561 DOI: 10.1039/FT9949002561

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements