Issue 24, 1994
From the journal:

Journal of the Chemical Society, Dalton Transactions

Preparation of new vanadium(II) iodides and crystal structure of hexakis(acetonitrile)vanadium(II)(tetraiodide)

Peter B. Hitchcock,   David L. Hughes,   G. Jeffery Leigh,   J. Roger Sanders,   Jaisa De Souza,   Celine J. McGarry  and  Leslie F. Larkworthy  

Abstract

The reaction of [VCl3(MeCN)3] with SiMe3I in acetonitrile under reflux yielded a vanadium(II) cation [V(MeCN)6]2+ with a counter ion I42–. The latter is not symmetrical, though linear, and the reasons are discussed. The new compound diiodotetrakis(tetrahydrofuran)vanadium(II) is shown to be a versatile precursor for vanadium diiodides, such as [VI2(Et2PCH2CH2PEt2)2], the structure of which has also been determined.

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Article information

DOI
https://doi.org/10.1039/DT9940003683
Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 3683-3687

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Preparation of new vanadium(II) iodides and crystal structure of hexakis(acetonitrile)vanadium(II)(tetraiodide)

P. B. Hitchcock, D. L. Hughes, G. J. Leigh, J. R. Sanders, J. De Souza, C. J. McGarry and L. F. Larkworthy, J. Chem. Soc., Dalton Trans., 1994, 3683 DOI: 10.1039/DT9940003683

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