A new type of tetradentate amino phosphonate monoester has been synthesized by alkaline hydrolysis of the parent phosphonate diester; the crystal structure of its copper complex reveals a monoester ligand-bridged centrosymmetric dimeric five-co-ordinate copper(II) complex.
S. W. A. Bligh, N. Choi, S. Failla, P. Finocchiaro, A. Il'yasov, M. Libertini, C. M. McGrath, M. McPartlin and T. M. Woodroffe, J. Chem. Soc., Dalton Trans., 1994, 3333 DOI: 10.1039/DT9940003333
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