Tetradentate phosphinoamines N,N′-bis[2-(diphenylphosphino)phenyl]ethane-1,2-diamine (H2dpen) and N,N′-bis[2-(diphenylphosphino)phenyl]propane-1,3-diamine stabilize copper(I) complexes either by ligand-exchange reactions from labile [CuI(MeCN)4]+ or ligand-promoted reduction of a CuII Cl2·2H2O precursor; the structure of one of the products, [Cu(H2dpen)]BF4, has been determined.
F. Tisato, F. Refosco, G. Bandoli, G. Pilloni and B. Corain, J. Chem. Soc., Dalton Trans., 1994, 2471 DOI: 10.1039/DT9940002471
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