Issue 14, 1994
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis, characterization and photophysics of luminescent organogold(I) phosphines

Vivian Wing-Wah Yam  and  Sam Wing-Kin Choi  

Abstract

Reaction of [Au2(dmpm)Cl2] or [Au3(dmmp)Cl3] with an excess of organolithium reagent LiR in diethyl ether gave [Au2(dmpm)R2] or [Au3(dmmp)R3] in high yield [dmpm = Me2PCH2PMe2; dmmp = Me2PCH2P(Me)CH2PMe2; R = Me or C6H4OMe-p]. These compounds were found to be emissive both in the solid state and in fluid solutions. An excited-state redox potential of –2.0(1) V vs. sodium chloride saturated calomel electrode has been estimated for [Au3(dmmp)(C6H4OMe-p)3].

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Article information

DOI
https://doi.org/10.1039/DT9940002057
Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 2057-2059

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Synthesis, characterization and photophysics of luminescent organogold(I) phosphines

V. W. Yam and S. W. Choi, J. Chem. Soc., Dalton Trans., 1994, 2057 DOI: 10.1039/DT9940002057

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