Issue 10, 1994

Delton communications. Synthesis and characterization of a palladium–osmium mixed-metal cluster; crystal structure of [Os6Pd(CO)18(bipy)]·CHCl3(bipy = 2,2′-bipyridine)

Abstract

The heterometallic cluster [Os6Pd(CO)18(bipy)](bipy = 2,2′-bipyridine) has been isolated in moderate yield from the reaction of [Os3(CO)10(MeCN)2] and [Pd(bipy)(CO2Me)2], and shown by a single-crystal X-ray structure analysis to contain a monocapped octahedral metal core with the palladium occupying one vertex of the octahedron.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 1605-1606

Delton communications. Synthesis and characterization of a palladium–osmium mixed-metal cluster; crystal structure of [Os6Pd(CO)18(bipy)]·CHCl3(bipy = 2,2′-bipyridine)

S. Chan and W. Wong, J. Chem. Soc., Dalton Trans., 1994, 1605 DOI: 10.1039/DT9940001605

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