An amphiphilic trinuclear cobalt cluster-containing molecular unit: synthesis, characterization and Langmuir–Blodgett films

Abstract

An amphiphilic polynuclear transition-metal cluster has been prepared and its capability for forming layers at the air–water interface and Langmuir–Blodgett films on different substrates investigated. The compound was obtained by linking a Co₃(CO)₉ cluster to a hydrophobic cholesterol framework. A polar head was introduced by substituting one CO ligand by an isocyanide derivative bearing a hydrophilic functional group. The surface pressure and surface potential vs.area isotherms and Brewster-angle microscopy indicated the formation of stable Langmuir films. Up to thirty-six transfers were performed on hydrophobized solids (mica, glass, quartz and silicon wafers). Structural characterization of the transferred films (UV and IR spectroscopy, atomic force microscopy, email-angle X-ray scattering) demonstrated the formation of stable, highly organized crystals. The results represent a novel strategy towards the development of supramolecular assemblies from polynuclear transition-metal compounds and organometallic surfaces. The structure of [Co₃(CO)₈(CCO₂Me)(CNC₆H₄CN)] has been established by X-ray crystallography.