Issue 7, 1994
From the journal:

Journal of the Chemical Society, Dalton Transactions

The kinetics of the reaction of [Ru(Cl)H(PPh3)3] with various olefins

Guiseppe Alibrandi  and  Brian E. Mann  

Abstract

A detailed kinetic investigation of the reaction of [Ru(Cl)H(PPh3)3] with cycloheptatriene, cyclohepta-1,3-diene, cyclooctatetraene, penta-1,4-diene. cycloocta-1,5-diene and dimethyl maleate, has been carried out spectrophotometrically in CH2Cl2 at 10 °C. It is shown that the major mechanism is viadissociation of PPh3 to give [Ru(Cl)H(PPh3)2] which then reacts with the olefin. There is also a second mechanism involving direct attack of the olefin on [Ru(Cl)H(PPh3)3].

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Article information

DOI
https://doi.org/10.1039/DT9940000951
Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 951-954

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The kinetics of the reaction of [Ru(Cl)H(PPh3)3] with various olefins

G. Alibrandi and B. E. Mann, J. Chem. Soc., Dalton Trans., 1994, 951 DOI: 10.1039/DT9940000951

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