The crystal structure of trans-[Rh(CO)(PPh3)2(OClO3)] has been determined, and it has been established that the perchlorate group is easily displaced by substituted hydrazines to give trans-[Rh(CO)(PPh3)2L]ClO4(L = NH2NH2–xRx; x= 1 or 2; R = Me or Ph). X-Ray crystallography shows that for all these complexes the unsymmetrically substituted hydrazine co-ordinates to rhodium viathe NH2 group.
C. J. Davies, I. M. Dodd, M. M. Harding, B. T. Heaton, C. Jacob and J. Ratnam, J. Chem. Soc., Dalton Trans., 1994, 787 DOI: 10.1039/DT9940000787
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