Issue 2, 1994
From the journal:

Journal of the Chemical Society, Dalton Transactions

Stereoselective photocatalysis of helical ruthenium(II) complexes in the reduction of racemic tris(acetylacetonato)cobalt(III)

Katsutoshi Ohkubo,   Taisuke Hamada,   Hitoshi Ishida,   Mitsuhiro Fukushima,   Megumi Watanabe  and  Hisayoshi Kobayashi  

Abstract

The Stereoselective photoreduction of rac-[Co(acac)3](Hacac = acetylacetone) possessing molecular helicities [P(C3) for Δ and M(C3) for Λ] by several ruthenium(II) photocatalysts having either P(C3) or M(C3) helical symmetry was successfully performed with a maximum enantiomeric excess of 38.7% at 40% conversion {to [Co(acac)2(H2O)2]} in EtOH–H2O (7 : 3) at 25 °C with an enantiomer rate ratio kΔ/kΛ of 5.2 : 1.

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Article information

DOI
https://doi.org/10.1039/DT9940000239
Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 239-241

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Stereoselective photocatalysis of helical ruthenium(II) complexes in the reduction of racemic tris(acetylacetonato)cobalt(III)

K. Ohkubo, T. Hamada, H. Ishida, M. Fukushima, M. Watanabe and H. Kobayashi, J. Chem. Soc., Dalton Trans., 1994, 239 DOI: 10.1039/DT9940000239

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