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Issue 19, 1994
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Concise synthesis of arogenate. A biosynthetic precursor of phenylalanine and tyrosine

Abstract

A concise new route to arogenate [L-(8S)-β-(1-carboxy-4-hydroxy-2,5-cyclohexadien-1-yl)alanine diammonium salt]1 in which Michael addition of the anion derived from methyl 1,4-dihydrobenzoate 2 to the dehydroalanine derivative 3 is the key C–C bond-forming step is described.

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Article type: Paper
DOI: 10.1039/C39940002237
Citation: J. Chem. Soc., Chem. Commun., 1994,0, 2237-2238
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    Concise synthesis of arogenate. A biosynthetic precursor of phenylalanine and tyrosine

    M. J. Crossley and R. C. Reid, J. Chem. Soc., Chem. Commun., 1994, 0, 2237
    DOI: 10.1039/C39940002237

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