Experiments based on the use of 18O2 and electrospray mass spectrometry show that during the conversion of precorrin-3A 1 into precorrin-3B 2 or precorrin-4 3 just one atom of oxygen is incorporated.
A. I. D. Alanine, Y. Li, N. P. J. Stamford, F. J. Leeper, F. Blanche, L. Debussche and A. R. Battersby, J. Chem. Soc., Chem. Commun., 1994, 1649 DOI: 10.1039/C39940001649
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