The first route to the side chain of Taxol and Taxotere, employing asymmetric epoxidation (AE) of trans-cinnamyl alochol and a new highly regio- and stereo-selective opening to the epoxide ring with MgBr2, is described.
C. Bonini and G. Righi, J. Chem. Soc., Chem. Commun., 1994, 2767 DOI: 10.1039/C39940002767
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