Reactions of 2-allyloxybenzylamines with H2/CO in the presence of rhodium catalysts give 1,3-benzoxazines via a reaction which involves allylic cleavage and carbonylation as demonstrated by crossover experiments.
E. M. Campl, W. R. Jackson, Q. J. McCubbin and A. E. Trnacek, J. Chem. Soc., Chem. Commun., 1994, 2763 DOI: 10.1039/C39940002763
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