Issue 23, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Halide abstraction from [(η5-C5H5)NbCl4] leading to novel cationic niobium(V) species: crystal structure of the ‘double’ hexachloroantimonate(V) salt [(η5-C5H5)NbCl(MeCN)4]3+[(η5-C5H5)Nb(MeCN)6]4+[SbCl6]7·7MeCN

Gerald R. Willey,   Mark L. Butcher,   Timothy J. Woodman  and  Michael G. B. Drew  

Abstract

Sequential removal of chloride ions from [(η5-C5H5)NbCl4] can be realised using antimony(V) chloride in acetonitrile under controlled stoichiometry; the formation and structural characterisation of the novel Nb(V) cations [(η5-C5H5)NbCl(MeCN)4]3+ and ([η5-C5H5)Nb(MeCN)6]4+ are described.

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Article information

DOI
https://doi.org/10.1039/C39940002721
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2721-2722

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Halide abstraction from [(η5-C5H5)NbCl4] leading to novel cationic niobium(V) species: crystal structure of the ‘double’ hexachloroantimonate(V) salt [(η5-C5H5)NbCl(MeCN)4]3+[(η5-C5H5)Nb(MeCN)6]4+[SbCl6]7·7MeCN

G. R. Willey, M. L. Butcher, T. J. Woodman and M. G. B. Drew, J. Chem. Soc., Chem. Commun., 1994, 2721 DOI: 10.1039/C39940002721

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