Issue 23, 1994

Stereoselective induction of an axiel chirality by Suzuki cross coupling of tricarbonyl(arene)chromium complexes with arylboronic acids

Abstract

Tricarbonyl(2,6-disubstituted-1-bromobenzene)chromium was treated with ortho-substituted phenylboronic acids in the presence of a palladium(0) catalyst to give mono-Cr(CO)3 complexes of biphenyl componds with a complementary axial chirality depending upon the nature of ortho-substituent of the phenylboronic acids

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2697-2698

Stereoselective induction of an axiel chirality by Suzuki cross coupling of tricarbonyl(arene)chromium complexes with arylboronic acids

M. Uemura and K. Kamikawa, J. Chem. Soc., Chem. Commun., 1994, 2697 DOI: 10.1039/C39940002697

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