Issue 22, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Preparation and reactivity of the first yttrium porphyrinogen complex

Jayne Jubb,   Sandro Gambarotta,   Robbert Duchateau  and  Jan H. Teuben  

Abstract

Reaction of Li4(thf)4(oepg)(oepg = octaethylporphyrinogen with YCI3(thf)3.5 affords the first yttrium porphyrinogen complex [Li(thf)2][(oepg)Y(µ-OEt)Li(thf)]1via intermediate cleavage of thf, subsequent reaction with alkyl and hydride sources leads to the formation of the demetallated dienolate salt of the macrocycle [(oepg)(thfLi)4][LiOCH[double bond, length half m-dash]CH2]22.

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Article information

DOI
https://doi.org/10.1039/C39940002641
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2641-2642

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Preparation and reactivity of the first yttrium porphyrinogen complex

J. Jubb, S. Gambarotta, R. Duchateau and J. H. Teuben, J. Chem. Soc., Chem. Commun., 1994, 2641 DOI: 10.1039/C39940002641

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