Reaction of the azasilavanadacyclobutane ring of the monomeric [V{(Me3Si)2N}{CH2SiMe2N(SiMe3)}(py)] with isonitrile gave insertion and ring expansion, while the same reaction carried out with the metallacycle of the dimeric [V{(Me3Si)2N}{CH2SiMe2N(SiMe3)}]2 formed an ionic and tetravalent [V{(Me3Si)2N}3]CN complex.
P. Berno and S. Gambarotta, J. Chem. Soc., Chem. Commun., 1994, 2419 DOI: 10.1039/C39940002419
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