Issue 20, 1994

Anodic cyclization of unsaturated α-stannyl ethers. Termination by bromide derived from dibromomethane

Abstract

Anodic oxidation of unsaturated α-stannyl ethers in Bu4NClO4–CH2Br2 results in effective cyclization and the introduction of bromide into one of the original olefinic carbons; a mechanism involving the coupling between the cyclized carbocation and Br generated by cathodic reduction of CH2Br2 is suggested.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2361-2362

Anodic cyclization of unsaturated α-stannyl ethers. Termination by bromide derived from dibromomethane

J. Yoshida, K. Takada, Y. Ishichi and S. Isoe, J. Chem. Soc., Chem. Commun., 1994, 2361 DOI: 10.1039/C39940002361

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