Octaethylporphyrinato rhodium cation dimer, [(OEP)Rh]2+2: strong dimer bonding resulting from both rhodium(II)–rhodium(II) and interporphyrin cation radical interactions
Abstract
Octaethylporphyrinato rhodium cation, [(OEP)Rh]+, forms a dimer, [(OEP)Rh]2+2, that is tightly bound through both a RhII–RhII bond and interporphyrin cation radical π–π interactions.