Unusual functionalization of C60via hydrozirconation: reactivity of the C60–ZrIV complex vs. alkyl–ZrIV complexes
Abstract
The reaction of the C60 hydrozirconation adduct 1 with N-bromosuccinimide and m-chloroperbenzoic acid leads to the formation of Diels–Alder products with bromo- and hydroxy-cyclopentadiene, respectively.
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